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Beilstein J. Org. Chem. 2014, 10, 1239–1245, doi:10.3762/bjoc.10.123
Graphical Abstract
Scheme 1: Regioselectivity of coupling reactions of 3-substituted thiophenes with aryl halides.
Scheme 2: Regioselectivity of the arylation of 2-methylthiophene with ortho-substituted aryl bromides.
Scheme 3: Direct arylation of 3-substituted thiophenes with 2-bromo-1,3-dichlorobenzene.
Scheme 4: Pd-catalysed C2-arylation of 8b with aryl bromides.